The isotropic-nematic phase transition in hard, slightly curved, lens-like particles.

نویسندگان

  • Giorgio Cinacchi
  • Alessandro Tani
چکیده

Monte Carlo numerical simulations are used to study in detail how the characteristics of the isotropic-nematic phase transition change as infinitely thin hard platelets are bent into shallow lens-like particles. First, this phase transition in the former reference model system is re-examined and more accurately located. Then, it is shown quantitatively that this already quite weak but distinctly first-order phase transition weakens further upon curving the platelets to such an extent that, thanks to the thinness of these particles that does not favor its pre-emptying by a transition to a (partially) positionally ordered phase, an isotropic-nematic tricritical point limit can be arbitrarily closely approached.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 141 15  شماره 

صفحات  -

تاریخ انتشار 2014